Articles in Press

The regulatory framework of heavy metal pollution associated with electronic waste is prevalent all over the world. As a result of technological advancement and change in consumer patterns, the life span of electrical and electronic products has been shortened. This has contributed to the emergence of massive amounts of electronic waste that needs to be handled. With the exponential growth of the telecommunications sector, the recycling of useful resources from electronic waste devices, especially mobile phones, is of great significance. Besides, the presence of valuable metals enables the recycling of electronic waste potentially appealing. In this research, numerous types of ionic liquids like Butyl methylimidazolium hexafluorophosphate [Bmim][PF6], Butyl methylimidazolium chloride [Bmim][Cl], Ethyl methylimidazolium chloride [Emim][Cl] and Butyl methylimidazolium tetrafluoroborate [Bmim][BF4] were used to analyze the copper leaching behavior of electronic mobile handset devices. Several influential aspects on the leaching efficiency of copper including different types of ionic liquid, temperature and leaching time have been examined. The findings showed [Bmim][PF6] and [Emim][Cl] were better ionic liquids in appropriate conditions for high copper leaching rates.

Researches to foresee the possible effects of climate change on the environment and living beings for taking necessary precautions on time have increased in recent years. In the improvement of these studies, especially the reduction of estimation errors by downscaling the outputs of global climate models played an important role. In this study, a model that can predict monthly precipitation amounts in the future by using downscaling methods in different global climate models were applied in Antakya district of Hatay province, and the model results were evaluated. The predictive parameters for global climate models were determined using downscaling methods by applying correlation analysis for the study area. As a result of this analysis, it was seen that the air temperature and specific humidity values at the pressure level of 925 hPa and the geopotential height value at the 300 hPa pressure level had the best correlation for the years 1970-2005. The usability of three different global climate models (CanESM2, GISS-E2H, and CSIRO Mk 3-6-0) for the forecast of future rainfall in the Antakya district of Hatay province was investigated using multiple linear regression analysis, one of the downscaling methods. As a result of the statistical analysis, it was seen that the use of the downscaling method increased the accuracy of all prediction models.

In the present study the sorption efficiency of okra leave sorbent for As(III) and As(V) is demonstrated. Sorption reaction is pH and time dependent. The sorbent shows maximum removal of As(III) and As(V) at pH 7 and pH 6 respectively and equilibrium was achieved at 180 minutes. In isotherm study experimental data were explained by Freundlich and Flory-Huggins models. Maximum sorption capacities calculated by Freundlich Isotherm were 5672.0 μg g-1 and 13160 μg g-1 for As(III) and As(V) respectively. Psuedo-second order rate equation and Morris-Weber equation explained the kinetics of sorption reaction. Due to the presence of heterogeneous active sites on the sorbent, surface sorption as well as intra-particle diffusion occurred. Thermodynamically, sorption reaction was endothermic in nature and proceeded spontaneously. Desorption study revealed that 89.82% of As(III) and 97.11% of As(V) were removed with 1M HCl.

Production of glycerol carbonate (GLC) that is a fuel additive from green solvent dimethyl carbonate (DMC) and biodiesel by-product glycerin is environmentally friendly synthesis. The usage of waste glycerol from biodiesel plant makes the production cost lower. When the membrane aided technique is used for the production of GLC, this technique will be very promising technique. Because membrane applications are environment and energy friendly economical applications. The production with membrane aided can be made by catalytic membrane. In this study, catalytic membranes were developed from synthetic and natural materials to produce GLC by transesterification reaction between glycerol and DMC. The reaction gives methanol as byproduct. The catalytic membranes were used methanol retentive material for increasing the reaction conversion of glycerol to glycerol carbonate. The synthetic catalytic membrane materials were poly(vinylalcohol)(PVA), poly(vinylpyrrolidone) (PVP), Poly(4-vinylpyridine) (P4VP) polymers and CaO. The natural catalytic membrane material was chitosan biopolymer and waste eggshell. The properties of by-product methanol retentive of the polymeric membranes were determined from sorption tests. The tests were shown that the catalytic membranes would sorp by-product methanol during reaction. This pointed out that GLC synthesis can be made by membrane aided technique such as membrane reactor.