Articles in Press

This study explored the best-operating conditions for a novel electrocoagulation (EC) reactor with the rotating anode for textile wastewater treatment. The influence of operating parameters like inter-electrode distance (IED), current density (CD), temperature, pH, operating time (RT), and rotation speed on the removal efficiency of the contaminant was studied. A comparative study was done using conventional model with static electrodes in two phases under same textile wastewater The findings revealed that the optimal conditions for textile wastewater treatment were attained at RT = 10 min, CD = 4 mA/cm2, rotation speed = 150 rpm, temperature = 25oC, IED = 1cm, and pH = 4.57. The removal efficiencies of colour, biological oxygen demand (BOD), turbidity, chemical oxygen demand (COD), and total suspended solid (TSS) were 98.50%, 95.55%, 96%, 98% and 97.10% within the first 10 min of the reaction. The results of the experiment reveal that the newly designed reactor incorporated with cathode rings and rotated anode impellers provide a superior treatment efficiency within a short reaction time. The novel EC reactor with a rotating anode significantly enhanced textile wastewater treatment compared to the conventional model. The values of adsorption and passivation resistance validated the pollutants removal rate.

Waste mobile phone is one of the subgroups of e-waste which is defined as discarded electronic products in the Philippine context. This study estimated current and projected quantities of waste mobile phones in the country using feed forward neural network. The neural network architecture used had three layers: (i) input layer, (ii) hidden layer, and (iii) output layer. Seven input factors were fed to the network: (i) population, (ii) literacy rate, (iii) mobile connections, (iv) mobile subscribers, (v) gross domestic product (GDP), (vi) GDP per capita, and (vii) US dollar to Philippine peso exchange rate. These input factors were selected based on the criteria provided in the study by the Groupe Spéciale Mobile Association (GSMA) Intelligence in 2015 on why the Philippines is an innovation hub in mobile industry and the availability of data from the sources. The structure was designed with five hidden layers which consisted of (i) six neurons for layer 1, (ii) five neurons for layer 2, (iii) four neurons for layer 3, (iv) three neurons for layer 4, and (v) two neurons for layer 5. The neural network was designed to initially calculate the sales of mobile phones before estimating waste mobile phone generation. Visual Gene Developer 1.7 Software was used which achieved a sum of squared error of 0.00001. Estimated values were found to be in good agreement with a calculated accuracy of 99%. This study can be used by policy makers as basis for strategy formulation and as guideline and baseline data for establishing a proper management system. Neural network performed better than the traditional linear extrapolation method for forecasting of data.

In this study, the potential use of Azolla filiculoides Lam. for the bioremediative solution to polycyclic aromatic hydrocarbon (PAH) pollution due to crude oil spills in freshwater was investigated. The plants were grown in nitrogen-free Hoagland nutrient solution media containing 0.05%, 0.1%, 0.2%, 0.3%, 0.4% and 0.5% crude oil by volume for 15 days under greenhouse conditions. Relative growth rates of A. filiculoides decreased in the presence of crude oil in a concentration-dependent manner. The probable influence of A. filiculoides on the biodegradation of polycyclic aromatic hydrocarbons was measured by using synchronous UV fluorescence spectroscopy. GC-MS analysis were also carried out to elucidate the behavior of the oil in experimental and control samples. Although 1-2 rings PAHs have not been encountered in control or plant samples, the measured intensity for 3-4 ring PAHs in plant samples was remarkably lower in comparison to the control. Furthermore, these results demonstrated that the predominant efficacy of the A. filiculoides was for 3-4 ring PAHs at the range 0.05 to 0.2% crude oil concentrations. It could be concluded that the bioremediative potential of A. filiculoides for the removal of polycyclic aromatic hydrocarbons strongly depends on the amount of oil in the contaminated water resource. In other words, A. filiculoides could be used more effectively after the removal of excess crude oil in the spilled freshwater areas.

The Membrane Bio-Reactor (MBR) technology offers a series of environmentally-friendly advantages, such as high quality effluent, pathogens removal capacity and avoided use of chemicals for disinfection, allowing it to be regarded as an environmentally friendly technology, when applied for wastewater treatment. However, membrane fouling still remains a major drawback, preventing its widespread application for municipal or industrial wastewater treatment. The use of additives (i.e. adsorbents, bio-carriers etc.) is considered to be among the major strategies implemented for membrane fouling control over the last few years. The present work examines the influence of bio-carriers addition, as well as of zeolite powder on the reversible and irreversible membrane fouling of a lab-scale MBR. High-strength synthetic municipal wastewater (with BOD5 around 1000 mg/L) was fed as the substrate for the activated sludge process and a flat-sheet microfiltration membrane was operated for solids (biomass) - liquid separation at the flux of 17 L/m2h. The obtained results showed that the addition of zeolite contributed mainly to the alleviation of irreversible fouling, leaving the reversible fouling practically unaffected, while the addition of bio-carriers had quite the opposite effect. In addition, it was shown that the lab-scale MBR system operated successfully, treating a high-strength synthetic municipal wastewater, as high removals were observed in terms of both organics and especially of ammonium removal (over 98%).