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Open Access | Published

Using wood and bone ash to remove metal ions from solutions

Chojnacka Katarzyna
Michalak
Abstract

In the present work, wood and bone ash were used to remove metal cations from solutions.
Cation-removal capacity of the ashes was analyzed by potentiometric titration. It was found
that the capacity of wood ash was two times higher (37.3 meq g-1) than bone ash (15.2 meq g-1).
Kinetics of metal ions removal by both ashes was described with pseudo-second order
equation and Langmuir model was employed to describe equilibrium of the process. Wood
ash had better removal properties than bone ash - at the same experimental conditions
biosorption capacity at equilibrium for wood ash was 2 times higher (244 mg g-1) than for bone
ash (123 mg g-1).
Promising results were also obtained for wood ash, which was capable of removing 67.9 % of
Zn(II) ions, 70.4 % of Cd(II) ions, 92.8 % of Cu(II) ions and 99.1 % of Cr(III) ions from model
solution of wastewater from metallurgical industry and 84.5 % of Cr(III) ions from the postbiosorption
solution from the production process of biological feed additives. The utilization of
ashes of biological origin was found to be a promising alternative to conventional processes
of wastewater treatment.

Keywords
wood and bone ash, kinetics, Equilibrium, III, Cr, II, Cd, II, Zn, II, Cu, II, Ni, removal of toxic metal ions, Wastewater