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The present study observed the removal of the organic content from the real effluent water produced by the oilfields. The proposed treatment process was the adsorption technique using the moringa peels as adsorbing agent. The effect of processing parameters such as adsorbent dosage, contact time and pH has been investigated using the batch adsorption method. The Langmuir isotherm provided a better fit for the adsorption equilibrium data than the Freundlich isotherm. It was observed that organic content adsorption was dependent on pH. The maximum removals of organic content were 65.4 % and 94.1% for moringa and activated moringa peels respectively at pH =3, 120 min, 1.5 gm dose. The outcome of this study exposes that activated moringa peels might be rummage-sale as a low-cost adsorbent for the removal of organic content from produced water.

Air pollutant emissions and fuel consumption of vehicles equipped with internal combustion engines are highly susceptible to the conditions of engine operation. The purpose of this research was to investigate the correlation between the emissions of individual pollutants (carbon monoxide, hydrocarbons, nitrogen oxides, and carbon dioxide), the fuel consumption and various dynamic conditions of the operation of an engine. The empirical data was obtained by testing of passenger car with a spark-ignition engine on a chassis dynamometer in 12 various driving tests, both type-approval and special. The results indicate, that the strongest correlation exists between the emissions of carbon dioxide and hydrocarbons and between the fuel consumption and the emissions of hydrocarbons and carbon dioxide. The weakest correlation was found to be between the emissions of carbon monoxide and nitrogen oxides. The average value of vehicle velocity proved to be suitable zero-dimensional characteristic of the dynamic driving conditions. The correlation between the emission of hydrocarbons and the average vehicle velocity can be assessed as the strongest, while between the emission of nitrogen oxides and the average vehicle velocity – the weakest.

Abstract: Water is the main factor of movement and transport of pesticides and contamination of water by these pollutants is one of the most important challenges due to their widespread use and increased concentrations. Moreover, these compounds are on the U.S.EPA Priority Pollutant list because of the potential of accumulation and the property of damaging effects. In this study, multiwalled carbon nanotube-based magnetic nanoparticles were synthesized and used as an affective adsorbent for carbaryl pesticide. The properties of the synthesized Fe3O4@MWCNTs were characterized by TEM images and XRD analysis. The obtained data were studied by isotherm and kinetic models. Carbaryl adsorbed onto the synthesized adsorbent was compatible with the Langmuir isotherm (R2 =0.993). The maximum adsorption capacity (qmax) of the pesticide onto the Fe3O4-MWCNTs was obtained at 68.2 mg/g. The kinetic studies of the reactions showed that the adsorption process followed the pseudo-second order model with R2 ≥0.99 for all initial carbaryl concentrations. The adsorbent was extracted by magnet reused several times (six rounds) with a reasonable efficiency. The Fe3O4-MWCNTs have great potential for adsorption of carbaryl from water and wastewater due to high efficiency, easy separation and reusability.

The long start-up time and high demand of anaerobic ammonium oxidation (anammox) limit the practical applications of the anammox process. In this study, granular sludge supported on activated carbon (AC) was used as seed sludge. The start-up time of the reactor was substantially shortened, and the expanded granular sludge bed (EGSB) reactor could be started quickly (in only 17 days). The nitrogen load rate (NLR) increased from 0.61 kg m-3 d-1 to 1.19 kg m-3 d-1, the removal rate of total nitrogen (TN) increased from 78.04% to83.15%, and the final ratio NH4+: NO2-: NO3- was 1:1.33:0.30. Moreover, in the gas analysis phase, the reactor load could be further improved and increased to 1.70 kg m-3 d-1 from the 18th–22nd day, and the reactor run stably. During this period, N2O and CO2 production was 0.8% and 0.02%, respectively. According to the analysis of microorganisms, the main functional microorganism in the reactor was Candidatus Kuenenia. The content of Candidatus Kuenenia increased by 5.45% after the reactor was started successfully. The color of sludge was brick red. This showed that the operation mode and inoculated sludge employed in this study are highly effective for the fast start-up of an EGSB reactor.