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The identification of PM sources and their contribution to measured PM concentrations is crucial for the environmental policy making since the findings be able to conduce to the development of relevant legislation in order to achieve effective air quality manage. In this study, the sources of PM10 at three receptors with different characteristics, within the Western Macedonia (WM) in NW Greece, were investigated: S1 in the center of Kozani, a medium sized city located at the southern edge of the industrial axis of WM, where urban activities and traffic density occur. S2 in the city of Ptolemaida, a medium sized city located in the centre of industrial zone, and S3 in the village of Eratyra, a rural residential district outside of the industrial area. For this purpose the multivariate Positive Matrix Factorization (EPA PMF 5.0) receptor model was applied on elemental data. Specifically, PM10 samples, obtained by filtration during 1-year sampling campaign, were analyzed by ICP-MS instrument. Twenty five elements were detected at quantifiable concentrations in the investigated PM samples. For the particle samples obtained in areas within and proximal from mining and power station operations, a six-factor model gave source profiles that attributed to be vehicle exhaust, road dust, soil dust, coal combustion, oil combustion and biomass burning. Furthermore, at the background site, the major contributors were biomass burning, soil dust and oil burning while no distant transport from industrial axis was recorded.

This study focuses on the impact of climate change on rainfall-runoff pattern, and to assess the surface runoff and groundwater recharge potential from the intensified rainfall for the effective management of surface and groundwater resources in Tirunelveli city. The rainfall contribution is consistent, dependent, maximum and intensified during the month of November followed by October and December. The intensified rainfall in these months causes a temperature decrease and the climate becomes more and more colder than ever. The indices SPI and DI clear show that there is a change in climatic pattern. Landuse Landcover (LULC) analysis shows that the residential area and mining area is on the increasing trend, Village area is slightly increasing, agricultural area and dense scrub area is on the decreasing trend. The present capacity of the storage tanks available in Tirunelveli city is less than the maximum runoff generated during the month of November. The increase in residential area in LULC reflects the direct linear relation with the population increase of the city. The impact of urbanization leads to LULC change with the loss of agricultural land and water bodies.

Volatile Organic Compounds (VOCs) are toxic for the environment and human health and their tendency to readily volatilize in the atmosphere can lead to problems connected to odours annoyance. Conventional VOCs gaseous emissions treatments entail the application of chemical-physical processes, only promoting the transfer of the contaminants from gas to liquid and/or solid phases. Advanced Oxidation Process (AOPs) and biological processes, conversely, support the oxidation of the organic pollutants, promoting their conversion into harmless and odourless compounds. The integration of booth processes is suggested to increase treatability of VOC. The research presents the application of an innovative treatment system composed by an AOPs pretreatment coupled with a bio-scrubbing unit for the abatement of VOCs, with the aim to increase the removal efficiency. The evaluation of the performance of the proposed system is discussed with reference to the analysis carried out using toluene as model substance. Different operating conditions have been analyzed and investigated to optimize the removal efficiency. The results show that the ozonation applied as pretreatment to the biological process may promote an increase of the pollutant biodegradability along with synergic effects due to the absorption of the ozone derived compounds into the culture growth, resulting in a significant enhancement of removal performances respect to the conventional biotechnologies. A toluene removal efficiency up to 95% were obtained under the investigated conditions.

The current study explores the capacities of Moringa oleifera (L), to overcome and/or tolerate oxidative stress induced by a saline substrate as a constraining factor. For this, Moringa seeds have been treated for 15 days after germination in vitro with increasing concentrations of NaCl, and specifically at 0 (control), 5; 7.5; 10; 12.5 and 15g l-1. Morpho-physiological and biochemical aspects were evaluated which were considered as probable indicators of tolerance or sensitivity to this stress. Our results reveal an increased synthesis of proline, lipids, proteins, CAT, GPX, APX, flavonoids, condensed tannins and a decrease in total polyphenols (-29.97%), mainly due to their high carbon cost. The state of degradation of the cell membranes was evaluated by the MDA assay, which increased by 91.25%. On the other hand, the evaluation of the oxidative damage caused by Reactive Oxidative Species (ROS) was detected by H2O2, which decreased by 37.89%. Additionally, our results revealed a disturbance of the germinative power of the seeds indicating moderate resistance to stress as it was manifested by the development of epicotyledonary axes, even under 15 g l-1 of NaCl without showing symptoms of stress or sensitivity. This result supports our hypothesis of the ability of the species to maintain or even improve its oxidative status.