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In order to investigate the effect of treated wastewater on heavy metals and fecal coliform in plant and soil, a field experiment was conducted in RCBD with three treatments in four replications during 2016-2017 in Borkhar, Isfahan (Iran). Treatments including well water, semi-treated wastewater and combination of well water and wastewater were applied in consecutive cultivation of wheat and forage corn. The amount of heavy metals in the soil did not change after two seasons of wastewater application compared to well water. The amount of fecal coliform in both plants was increased in the irrigation water treatment compared to the well water, which was more evident in the corn plant, which is related to the high moisture content of this plant at harvest stage. Due to the improvement of soil nutrient concentrations after two seasons of continuous application of wastewater and no increase in the amount of heavy metals in the soil, the use of wastewater for agricultural production is permissible. But according to the fecal coliform index, it is recommended not to be used for the production of crops harvested at high humidity and conditions for the survival of pathogens.

Contamination of groundwater by chlorinated solvents such as trichloroethylene (TCE, tetrachloroethylene (PCE), and 1,1-dichloroethylene (1,1DCE) is a widespread problem that can seriously threaten human health and the environment. These compounds are often present as dense nonaqueous phase liquid (DNAPL) mixtures in the subsurface that serve as a long-term groundwater contamination sources. The objective of this study is to test the effectiveness of different in-situ flushing agents (SDS, Tween 80, MCD, and water) for the recovery of DNAPL mixtures (TCE, PCE, 1,1DCE) entrapped in heterogeneous aquifer media. A series of batch tests were first performed to assess the multiphase behavior of water-DNAPL mixture-reagent system. Intermediate scale tank experiments were then performed to compare the performance of the reagent solutions. The flushing breakthrough curves were also used to investigate the impact of solubilization agents on mass-flux reduction/mass-removal behavior relationships. Performance of agents on DNAPL mixture source zone remediation was found to be in the following order: Tween 80>SDS>MCD>>Water. Individual DNAPL constituents exhibited transient effective solubilities that depend on the reagent contents and DNAPL compositions. Although high fractions of DNAPL source zones in heterogeneous porous media were removed through chemical flushing (SDS, Tween 80, MCD, and water), the heterogeneous system exhibited an extended multi-step concentration behavior. The results emphasized that in the early stage, some portion of the organic liquid is hydraulically accessible (matrix) whereas the later stage of mass removal was controlled by the more poorly accessible mass (pool) associated with higher-saturation zones. Our results also showed that the distribution and the emplacement of organic liquid, flow-field heterogeneity, sorption and desorption, and flushing solution all influenced the DNAPL mixture removal. The results from this study underline the need for understanding the multiphase behaviour of a system, particularly when DNAPL mixtures are present, prior to field-scale remediation implementation.

The Mediterranean region is expected to present reduced availability of water resources due to climate change. This study aims to assess the potential hydrological responses to climate change in the Kastoria basin (Western Macedonia, Northern Greece) for the period 2019-2078. Climate projections from eight regional climate models from EURO-CORDEX were bias-adjusted using the linear scaling method. The bias-adjusted climate data were used to force the FeFLOW hydro-logical model to predict the discharge of the Kastoria aquifer towards lake Orestiada along with the projected groundwater level distribution. Precipitation (temperature) shows a tendency to decrease (increase) mainly in late spring to early autumn while increase (decrease) in the other sea-sons. Moreover, results indicate a significant increase in temperature and a slight decrease in precipitation towards 2078, while the predicted groundwater level of Kastoria aquifer will reduce slightly. However, the future hydrological behavior of the basin indicates a substantial reduction by approximately 15% of total water yield towards the end of the century.

The dumping of solid waste in uncontrolled landfills can cause significant impacts on the environment and human health. The open dumps cause the formation of leachate which contaminated the groundwater; use of these groundwater reported danger to the human health. The goal of groundwater protection is necessary to control the release and migration of pollutants from the leachate in the subsurface. In this paper, the above-mentioned problems were dealt with the case study of Ariyamangalam open dumping site, Tiruchirappalli, Tamilnadu. The dump site receives 71% of organic waste. The groundwater flow and leachate transport model was developed using Visual MODFLOW and MT3DMS (Version 4.3), to study the leachate transport in the subsurface and to predict the plume behavior under different scenarios. The conceptual model of the system was derived from the information on geology, geo physical and geo hydrology of the study area. The total dissolved solids (TDS) were taken as a parameter, to study the extent of contaminant plume for the next nine years (2014-2022). From the groundwater flow model, it was found that the increase in water level by 2.5 m above MSL from December 2010 (70.9 m above MSL) to December 2022 (73.4 m above MSL) around the study area. From the leachate transport model, the predicted TDS plume movement was identified towards the west and south east directions of the open dumping area. As a conclusion, the developed groundwater flow and leachate transport model can be effectively used for studying the leachate migration from the open dumping site into subsurface system.