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Three different advanced oxidation processes (AOPs) were applied to investigate the removal of emerging contaminants (ECs) i.e. sulfamethoxazole (SMX), diclofenac (DCF) and carbamazepine (CBZ) in synthetically prepared solutions. The degradation of these substances was carried out by ozonation, sonolysis and photocatalytic oxidation, as well as by different combinations of these processes. The objectives of this work were to evaluate the removal efficiency in each AOP and to assess the performance variation of sonolysis in combination with other AOPs. The best performances were achieved by sonocatalysis, which resulted in the removal of the selected pharmaceuticals in the range between 37% and 47%. Under similar experimental conditions, the removal of the selected ECs by single compounds by ozonation was slightly lower than the removal of respective compounds in the mixture. Moreover, pseudo first-order removal rate constants of photocatalytic mineralization were determined as 9.33×10-2, 4.90×10-3, 1.06×10-2 min-1 for SMX, DCF and CBZ, respectively.

With the increase in industrial and agricultural activities, huge amount of wastewater containing nitrogen is produced. Biological denitrification is currently the most widely used, sustainable and cost-effective process to remove nitrogen from wastewater. In biological denitrification, application of external carbon sources for denitrification is important because it is the way to boost the denitrification process and it is necessary for wastewater treatment plants that have to meet very stringent effluent nitrogen limits. This review study focused with treatment of wastewater using biological denitrification as advantages. This also deals with advantages of different external carbon sources with emphasis on biological denitrification as the cost of biological denitrification is controlled by the carbon source because the cost of biological denitrification is controlled by the carbon source.. Hence, use of alternative carbon sources such as agricultural wastes, and food waste is reviewed in this paper. This study recommend other waste material such as textile waste can be a part of denitrification because carbon source such as methanol, ethanol and acetic acid/acetate can be recovered from textile waste.

In this study, the application of Sn/Sb/Ni-Ti electrodes for the treatment of waste streams were investigated which is promising for ozone production by electrolysis of water because of their stability and high potential for ozone evolution reaction. These series of anodes have a high electrochemical ozone generation potential at ambient conditions (approximately up to 40% current efficiency). But using and testing of these novel anodes for real wastewater are too limited in the literature. Titanium mesh substrate coated with Sn/Sb/Ni-Ti alloy was used as anode immersed in wastewater at room temperature with platinized titanium cathode. These electrodes used for COD and color removal from OID wastewater in Inegol, Bursa, Turkey. Five operational parameters were evaluated for electrochemical COD and color removal processes, such as pH, salt content, applied voltage/current, current efficiency and contact time. Experimental results showed that after 30 min the electrochemical oxidation efficiency of COD and color could reach up to 98% and 99% respectively at pH 8.2 and temperature of 25°C as the optimum conditions. Current density observed as the most effective parameter for COD and color removal efficiencies. The lowest energy consumption was between 10-25 mA cm-2 of current density with only 0.6 kWh gCOD−1, while the highest energy consumption was 100 mA cm-2 of current density with 9.12 kWh gCOD−1 . The optimum current density value has been found as 50 mA cm-2 with 4.05 kWh gCOD−1 . These results were also supported with ANOVA test.

An adsorbent was prepared from Mangosteen shell using sulphuric acid and sodium bicarbonate as modifiers. Bicarbonate treated mangosteen shell (BTMC) was characterized using FT- IR, SEM, EDAX and XRD data. The Freundlich adsorption isotherm model gives a good fit. The maximum adsorption capacities of BTMC were found to be 58.48 mg g-1 and 49.75 mg g-1 for Pb (II) and. Hg (II). Adsorption of Pb (II) and Hg (II) followed pseudo-second-order kinetics. The adsorption mechanism was explained using the Weber and Morris's intra-particular diffusion process. Batch mode studies with synthetic wastewater suggest that BTMC can be efficiently used in wastewater treatment.