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The temperature, feed rate, length of mass transfer zone, utilization factor and partial pressure are the parameters considered for fixed bed sorption of CO2 from N2/CO2 mixture. The breakthrough time relies strongly on the temperature and feed rate. The prolonged breakthrough and saturation times have been realized for AC. The response curves of AC are vastly steep signifying the maximal utilization of bed capacity at the breakpoint. In general, the length of MTZ increases with raised temperature and feed flow rate. The capacity utilization factor reduces with raised temperature and feed flow rate. A utilization factor of 0.919 was determined for AC. The maximal capacity for CO2 reduces significantly with an increased temperature. The maximal capacities of 32.99 gm CO2/Kg was determined at a temperature of 298 K for AC. The capacity improves considerably with CO2 partial pressure and AC exhibited higher adsorption capacity compared to SG. The capacity improves considerably with increased feed rates and maximal capacity of 39.14 g CO2/Kg adsorbent was determined for AC at the feed rate of 8.33 x10-3 m3/sec. Owing to higher sorption capacity and utilization factor, the AC may be used for economical separation of CO2 from N2/CO2 mixture

The Amvrakikos Bay is one of the most important ecosystems in the Mediterranean with great environmental, ecological and biological value. However, over the years, water quality has suffered severe degradation and is now one of the most polluted environmental areas in Greece. In the present study, using the analytical data of concentrations of precipitated metal deposits at the bottom of Amvrakikos Gulf, at its three largest lagoons: Logaros, Tsoukalio and Rodia, and by applying the indicators PLI, Igeo and EF, an assessment of the level of pollution of the area was made. The use of these indicators may show the degree of pollution of the area with heavy metals, and reveal the source of pollution i,e. whether the heavy metals are of anthropogenic or of natural processes, assessing simultaneously the degree of anthropogenic effect. Based on the PLI indicator, the marine zone in Menidi and Paliovarka as well as the Rodia and Tsoukalio lagoons are considered to be polluted. According to the Igeo Index, the sampling areas are unchanged to slightly burden by heavy metals. The largest charge is caused by Ni, followed by Mn and Pb. Based on EF, the concentrations of Cr, Mn, Co, Pb and Ni are significantly influenced by the various anthropogenic activities.

In this research, capability of adsorption of modified chitosan Nano composites with functionalized mesoporous silica which synthesized by electrospinning method in the removal of direct black ANBN dye has been studied. Silicate mesoporous were functionalized during synthesis process and then the intended Nano fibers were produced by using of electrospinning device. Synthesized Nano fibers were recognized by analyzing the FT-IR, XRD, FE-SEM, and TEM and tension test. The removal of direct black ANBN dye from aqueous solution in a continuous system was done by this adsorbent by studying the effects of some parameters such as type and amount of adsorbent, pH, initial concentration of colored solution and contact time; And at the end finding appropriate isotherms for direct black dye adsorption was done. The result show that simple CTS/SBA-15 have the best removal efficiency in 40 min of contact time, in acidic pH, with 0.05 gr adsorbent and 60 mg/L initial concentration. By examining the adsorption isotherms, it has been clearly defined [that] Removal of this dye follows Freundlich model. In order to compare accurately and evaluate the efficiency of the synthesized sample, the adsorption of Direct Black ANBN was investigated by two different adsorbents: CTS/SBA-15 and Chitosan. According to the results, CTS/SBA-15 Nano fibers have suitable efficiency for removal of direct black ANBN dye.

The distribution, stocks and fluxes of Mo were examined in a mountainous fir forest in Greece in two hydrological years. In both years, the fluxes of Mo in throughfall were lower than those in bulk deposition implying Mo retention and probably uptake by tree canopies. The Mo concentration was appreciable in soil solution but its fluxes were lower than those in throughfall. The Mo fluxes in both bulk and throughfall deposition were higher than those in litterfall, a finding that stresses the importance of the hydrological cycle for this metal. The Mo concentration in the older twigs in the standing trees were higher than the current year ones most probably due to the existence of dry deposition. The concentrations of total Mo in soils reflected the nature of the sedimentary rocks underlying the soil and increased with depth following the clay concentration gradient. The available (oxalate extractable) Mo in soils ranged from 3% to 14% of the total Mo. In terms of the stocks of Mo, the soil had by far the highest values in both total and available Mo. The needs of the fir plants for Mo uptake are covered by the available Mo in the mineral soil layers, whereas the Mo content in the organic horizon may not be adequate for this purpose.