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Hydrological modeling of a watershed is necessary for water resources planning and management. The hydrology of upper Ribb watershed has been analyzed using spatially semi-distributed Soil and water assessment tool (SWAT) model. This study aimed to determine the water balance components and its relation with the rainfall which reaches to the surface of the earth. Different spatio-temporal (land use, soil, digital elevation model, climate data, river discharge) data were used for hydrological modelling of Upper Ribb watershed. The applicability of SWAT model in Upper Ribb watershed has been evaluated using coefficient of determination (R2) and Nash Sutcliff efficiency (NSE) parameters. The calibration results revealed the observed data showed a very good agreement with the simulated data with the R2 and NSE values of 0.90 and 0.84 respectively. Similarly, the validation results of streamflow were acceptable with the R2 and NSE values of 0.80 and 0.82 respectively. The monthly average streamflow from Upper Ribb watershed were found 13.39 m3/s. The major portion of the rainfall contributes to the surface runoff due to the major percentage of the watershed is covered with agricultural lands. The groundwater flow was high in forested areas, while evapotranspiration was found very high in water bodies (Ribb reservoir). In this study area the rainfall showed a direct relationship with the streamflow. The ratio of streamflow and evapotranspiration with rainfall was 0.61 and 0.36 respectively. Due to the presence of high amount of surface runoff and evapotranspiration the deep recharge which contributes to the ground water is not that much significant.

Ammonia (NH3) and hydrogen sulfide (H2S), as the main odorous substances in waste gas from livestock farm, have attracted more attentions rescently since their adverse effects. To remove NH3 and H2S efficiently, high-pressure hydrothermal modification (HPHM), metal salt solution impregnation modification (MSIM), and HPHM combined with MSIM are used to modify the activated carbon (AC). Meanwhile, the pore structure and surface functional groups of AC and MAC absorbents are characterized by BET, FTIR and Boehm titration method. The adsorption performance of activated carbon (AC) and modified activated carbon (MAC) are compared. The effects of modification and operation conditions on the adsorption performance of MAC for NH3 and H2S are studied in detail. It was found that the optimal adsorption performance of MAC can be achieved by high-pressure hydrothermal modification (HPHM) followed by the metal salt solution impregnation modification (MSIM). With gas space velocity of 900 h-1 and total inlet concentration of 550-650 mg m-3 at 50 oC, the adsorption capacities of NH3 and H2S of GS270CuCl6010 are 24.17 mg g-1 and 26.20 mg g-1, respectively. The adsorption of NH3 and H2S by MAC is the result of both physical adsorption and chemical adsorption.

Sustainability in textiles is now a day’s key demand of consumers and traders, where the process with zero effluent emission or less emission has been considered for aim to utilize the ecofriendly process in direct dyeing of cotton to minimize effluent load. For this purpose, variable amount of Table salt and Glauber salt has been used to achieve maximum exhaustion during direct cotton dyeing. Different dyeing variables have been employed, shade made at the optimum conditions were assessed according to ISO standards. It has been found that 3g/100mL of table salt for Direct dyeing of cotton using 40mL of DR 28 (8pH) at 65oC for 45 min, whereas using 40mL of DB 15 (8pH) for dyeing of cotton at 65 °C for 45min containing 3g/100mL of Glauber slat has given acceptable color characteristics. The reduction in dyeing variable using low salt amount has proved that this method is cost, time and energy efficient process, which can be utilized for dyeing of natural fabrics using various classes of dyes to obtain sustainable textile products.

Photo-Fenton for decreasing concentration of Pb(II) ions in the aqueous solution is systematically studied. The photo-Fenton process was carried out by batch technique, under UV light. The influences of process operating parameters were evaluated. The results of the research demonstrated that by photo-Fenton process, the concentration of Pb(II) ions in the aqueous solution can be decreased, that may be through oxidation mechanism by OH radicals. The decrease is found to be controlled by Fe2+ and H2O2 concentrations, as well as by the pH and the irradiation time. For 20 mg/L of Pb(II) in the 100 mL solution, the optimum condition of the oxidation is obtained to be 10 mmole/L of Fe2+, 200 mmole/L of H2O2, pH 3, and 90 min of the reaction time. It is also confirmed that the oxidation of Pb (II) by OH radical has formed the undissolved PbO2, that is less toxic and easier to be handled.