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This work analyzes the extraction behavior of transition heavy metal Zinc and other metal ions such as Copper, and Cadmium from hydrochloride aqueous solution in the absence of chelating agents by using a novel class of hydrophobic ionic liquids. Ionic liquid for this study was synthesized based on 1-(n-alkyl)-3-methylimidazolium cations and hexafluorophosphate anions followed by the metathesis route at room temperature were evaluated. The advantages of using these ionic liquids include their simple synthesis and sustainability. Which makes them “Greener and Simpler” compared to other solvents used for metal extraction. The experimental results show that ionic liquid 1-Butyl-3-methylimidazolium hexafluorophosphate, [BMPSM][PF6] entirely removed of Zinc (extraction percentage 94.4%) and other Copper and Cadmium heavy metals from the aqueous solutions. Based on the results, the use of ionic liquids for selected heavy metal ions as a substitute to the traditional extraction agents in liquid/liquid extraction of heavy metal ions shows considerable potential and is quite promising and promoting for further extraction.

In the presence of nitrogen oxides, nitrate-reducing bacteria (NRB) may use nitrate as an electron acceptor, reduce nitrate to nitrite, and finally convert nitrite to nitrogen or ammonium (NO and N2O). Studies have shown that BCX (Bio-Competitive Exclusion) is a viable , ecologically benign, and low-cost technique for regulating NRB in its first phases of study and application. More precisely, Pseudomonas sp. to isolate nitrate-reducing bacteria from oil-field wastewater using 16S rDNA sequencing and selection (NRB). Including NO3 and NO2 as bio-activators has helped researchers get a deeper understanding of the processes that govern NRB activation. The potential for molybdate and NRB to inhibit Sulfate-Reducing Bacteria (SRB) was also investigated. The results showed that NO2 was more effective than NO3. The effect was greatest at a 1:4 ratio of NO3 to NO2. NRB activation synergized with low molybdic acid solution concentrations (5%). Static corrosion model experiments demonstrated the importance of SRB in the corroding process. Biological inhibitors were shown to have the lowest corrosion rates, proving their effectiveness. Scanning electron microscopy was used to examine the corroded steel sheet's surface morphology. In addition, there was almost no surface corrosion or pitting on the steel sheet.

With the rising interest for sustainable power source and ecological security, anaerobic digestion of biogas technology has attracted considerable attention within the scientific researchers. This paper proposes a new research achievement on biogas production from Rice Mill Wastewater (RMW) with the utilization of anaerobic digester. An anaerobic digester is maintained with RMW and distillery anaerobic sludge at mesophilic temperature condition for 15 days as stabilization mode. After attaining stabilization stage, studies continued to examine the effect of Organic Loading Rate (OLR) and Hydraulic Retention Time (HRT) on the mesophilic anaerobic digestion of RMW. The OLR of the anaerobic reactor increased stepwise from 0.25 to 3.91 Kg COD/m3/dayand HRT ranged from 1 to 32.0 days. The total chemical oxygen demand (TCOD) utilized was higher than 75% and the CH4 percentage of the biogas was 62.00-63.00% for the OLRs studied. The efficient working volume of the digester is preserved as 25% of distillery anaerobic sludge and 75% of rice mill wastewater, loaded at Mesophilic temperature conditions for study purpose. By changing the conditions of OLR and HRT, biogas production, methane yield and percentage of COD reduction is examined. An anaerobic sludge is utilized as a seeding material to biodegrade the organic pollutants present in the wastewater. It will enhance the biological treatment of effluent with anaerobic sludge in a continuous mode of activity.The result showed that the proposed analysis obtains more biogas production with reduced COD when compared with existing approaches.

The Maluku Islands (henceforth MI) are situated in the northeastern Indonesia. Ocean region off the central MI is pivotal as it provides a course for the Indonesian Throughflow (ITF) through the Lifamatola passage. However, sea surface dynamics off the central MI is unknown until recently due to inadequate measurements. The current fact motivates the present study to decipher the coastal wind variability off the central MI and its effect on the sea surface by analysing long-term datasets (2007-2019) of satellite-derived sea surface wind, sea surface temperature (SST), and surface chlorophyll-a concentration. Possible influence of extreme climate events of the 2015 El Niño-Southern Oscillation (ENSO) and the 2019 Indian Ocean Dipole (IOD) on all oceanographic parameters was also examined. Results show that the prevailing southeasterly winds over the central MI induce SST cooling and phytoplankton bloom. Correlation analysis revealed that the ENSO and IOD play significant roles in defining spatial distribution of the coastal wind, SST, and phytoplankton bloom in the research area. In addition, the anomaly analysis exhibits distinct oceanographic features during the climate extreme events of 2015 and 2019. Collectively, results of the present research highlight the importance of coastal wind variability and extreme events in shaping the ocean surface characteristics and perhaps regional fisheries production.