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Contamination of groundwater by chlorinated solvents such as trichloroethylene (TCE, tetrachloroethylene (PCE), and 1,1-dichloroethylene (1,1DCE) is a widespread problem that can seriously threaten human health and the environment. These compounds are often present as dense nonaqueous phase liquid (DNAPL) mixtures in the subsurface that serve as a long-term groundwater contamination sources. The objective of this study is to test the effectiveness of different in-situ flushing agents (SDS, Tween 80, MCD, and water) for the recovery of DNAPL mixtures (TCE, PCE, 1,1DCE) entrapped in heterogeneous aquifer media. A series of batch tests were first performed to assess the multiphase behavior of water-DNAPL mixture-reagent system. Intermediate scale tank experiments were then performed to compare the performance of the reagent solutions. The flushing breakthrough curves were also used to investigate the impact of solubilization agents on mass-flux reduction/mass-removal behavior relationships. Performance of agents on DNAPL mixture source zone remediation was found to be in the following order: Tween 80>SDS>MCD>>Water. Individual DNAPL constituents exhibited transient effective solubilities that depend on the reagent contents and DNAPL compositions. Although high fractions of DNAPL source zones in heterogeneous porous media were removed through chemical flushing (SDS, Tween 80, MCD, and water), the heterogeneous system exhibited an extended multi-step concentration behavior. The results emphasized that in the early stage, some portion of the organic liquid is hydraulically accessible (matrix) whereas the later stage of mass removal was controlled by the more poorly accessible mass (pool) associated with higher-saturation zones. Our results also showed that the distribution and the emplacement of organic liquid, flow-field heterogeneity, sorption and desorption, and flushing solution all influenced the DNAPL mixture removal. The results from this study underline the need for understanding the multiphase behaviour of a system, particularly when DNAPL mixtures are present, prior to field-scale remediation implementation.

The Mediterranean region is expected to present reduced availability of water resources due to climate change. This study aims to assess the potential hydrological responses to climate change in the Kastoria basin (Western Macedonia, Northern Greece) for the period 2019-2078. Climate projections from eight regional climate models from EURO-CORDEX were bias-adjusted using the linear scaling method. The bias-adjusted climate data were used to force the FeFLOW hydro-logical model to predict the discharge of the Kastoria aquifer towards lake Orestiada along with the projected groundwater level distribution. Precipitation (temperature) shows a tendency to decrease (increase) mainly in late spring to early autumn while increase (decrease) in the other sea-sons. Moreover, results indicate a significant increase in temperature and a slight decrease in precipitation towards 2078, while the predicted groundwater level of Kastoria aquifer will reduce slightly. However, the future hydrological behavior of the basin indicates a substantial reduction by approximately 15% of total water yield towards the end of the century.

Numerical simulation was conducted to assess the impact of dust emission on typical environmental sites in Jinan City. The CALPUFF model was applied to five simulation scenarios. The results showed that dust emission had a significant impact on air quality in Jinan. The impact of dust emission on the average concentration of PM10 at 15 monitoring sites was 19.8 μg/m3, accounting for 14.9% of the annual total. The impact of dust emission on the average concentration of PM2.5 was 5.2 μg/m3, accounting for 8.1% of the annual total. Adoption of yellow warning measures in the emission reduction scenarios had insignificant environmental effects due to unfavorable meteorological conditions. Compared with the baseline scenario, the average concentrations of PM10 and PM2.5 decreased by 13.6% and 1.9%, respectively. After adoption of orange and red warning measures, the impact of site dust emission on air quality at the monitoring site was reduced significantly. Significant environmental effects were achieved after all construction sites within a 2-km radius of the monitoring site were closed. Compared with the baseline scenario, the average concentrations of PM10 and PM2.5 were reduced by 45.5% and 42.3%, respectively. The results showed that under adverse meteorological conditions, higher-level warning measures should be undertaken to reduce the impact of site emissions on environmental quality. Considering the economic and social effects of emission reduction, temporary construction stoppage within 2 km of the monitoring site is a feasible plan that is in accordance with the goals of comprehensive environmental management.

The dumping of solid waste in uncontrolled landfills can cause significant impacts on the environment and human health. The open dumps cause the formation of leachate which contaminated the groundwater; use of these groundwater reported danger to the human health. The goal of groundwater protection is necessary to control the release and migration of pollutants from the leachate in the subsurface. In this paper, the above-mentioned problems were dealt with the case study of Ariyamangalam open dumping site, Tiruchirappalli, Tamilnadu. The dump site receives 71% of organic waste. The groundwater flow and leachate transport model was developed using Visual MODFLOW and MT3DMS (Version 4.3), to study the leachate transport in the subsurface and to predict the plume behavior under different scenarios. The conceptual model of the system was derived from the information on geology, geo physical and geo hydrology of the study area. The total dissolved solids (TDS) were taken as a parameter, to study the extent of contaminant plume for the next nine years (2014-2022). From the groundwater flow model, it was found that the increase in water level by 2.5 m above MSL from December 2010 (70.9 m above MSL) to December 2022 (73.4 m above MSL) around the study area. From the leachate transport model, the predicted TDS plume movement was identified towards the west and south east directions of the open dumping area. As a conclusion, the developed groundwater flow and leachate transport model can be effectively used for studying the leachate migration from the open dumping site into subsurface system.