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A comprehensive study of the high temperature pyrolysis of sewage sludge: kinetics, energy analysis and products formationView Crossref metadata(active tab) <div id="edit-xml" class="form-item form-type-item"> <?xml version="1.0"?> <doi_batch version="4.4.1" xmlns="http://www.crossref.org/schema/4.4.1" xmlns:jats="http://www.ncbi.nlm.nih.gov/JATS1" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.crossref.org/schema/4.4.1 http://www.crossref.org/schemas/crossref4.4.1.xsd"><head><doi_batch_id>000692</doi_batch_id><timestamp>1713917471</timestamp><depositor><depositor_name>University of the Aegean</depositor_name><email_address>uoa@university.com</email_address></depositor><registrant>Global NEST Journal</registrant></head><body><journal><journal_metadata><full_title>Global NEST Journal</full_title><full_title>Global NEST: the international Journal</full_title><issn media_type="print">1790-7632</issn><issn media_type="electronic">2241-777X</issn></journal_metadata><journal_issue><titles><title>Issue 1</title></titles><publication_date><month>03</month><year>2024</year></publication_date><journal_volume><volume>24</volume></journal_volume><issue>1</issue></journal_issue><journal_article><titles><title>A comprehensive study of the high temperature pyrolysis of sewage sludge: kinetics, energy analysis and products formation</title></titles><abstract xmlns="http://www.ncbi.nlm.nih.gov/JATS1"><p><p>This study evaluates the pyrolysis of sewage sludge until 960 °C using heating rates between 3 K/min and 12 K/min in a macro TG/EGA. Mass and energy balances and kinetic parameters are determined. Thermal decomposition is divided into a low temperature zone (until 550 °C to 590 °C), for decomposition of organic matter, and a high temperature zone, for decomposition of inorganic matter and secondary reactions of the residual organic matter. In dry basis at 570 °C solid, liquid and gaseous products amount to 69.2 wt.-%, 29.2 wt.-% and 1.6 wt.-%, respectively. An increment in the final temperature to 960 °C causes a successive decrease of the solid residue to 56.9 wt.-%. The solid product contains more than 80 wt.-% mineral matter with high amounts of valuable elements, such as Ca and P. An energy requirement of 2.18 MJ/kg of dry sewage sludge is calculated for the pyrolysis until 570 °C. At this temperature, 58.5 % of the energy entering the process is concentrated in the liquid product and 40.0 % in the solid. A suitable set of kinetic parameters is determined through a formal independent parallel reactions model with six-pseudo components, using a combination of isoconversional and fitting methods.</p> </p></abstract><publication_date><month>12</month><day>23</day><year>2021</year></publication_date><pages><first_page>16</first_page><last_page>28</last_page></pages><publisher_item><identifier id_type="pii">gnest_03738</identifier></publisher_item><doi_data><doi>10.30955/gnj.003738</doi><timestamp>1713917471</timestamp><resource>https://journal.gnest.org/publication/gnest_03738</resource></doi_data></journal_article></journal></body></doi_batch> </div>
